BEHS Chemistry |
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Assignment directions for a project using water hardness
CheMystery Labs 380 South Buzz Blvd Bee Hive, UT 84302 Dear Team: The County Council of Governments would like to know how the total water hardness compares between various communities in the county. Some soft water costumers think their systems are being affected by excessive hard water provided by the community. The County Council of Governments has a budget of $60,000 to answer their question. Before you begin your work, I will need the following information from you so that I can approve your work. The planning space for these items is found in your project packet. Ø a detailed summary of your hypothesis, experimental design table, a plan for the procedures along with all necessary data tables Ø a description of necessary calculations Ø an itemized list of equipment with costs and chemical with their costs, include labor costs of $80 / hour and cost for laboratory space $10,000/day, and a standard disposal fee of $2000 / gram of material. After you complete the analysis, prepare a report for the County Council of Governments. Remember that this report will be seen by a variety of people, so be certain it projects the image we want to present. The items that should be included in the report are found in your project packet. Good luck with the project. Please keep in close contact me as you proceed with the project. You will need a data verification signature, by having me observe one of the trials in the experiment. Sincerely Your teacher President and CEO CheMystery Labs Inc. The Total Hardness Of Water In Local Water Supplies Background Information Hard water contains dissolved salts, especially those of calcium and magnesium. Hard water often contains magnesium and CaCO3 + H+ ---------> Ca2+ + HCO3- The reaction of water with atmospheric carbon dioxide makes rain water naturally slightly acidic. Unnatural acidic H2O + CO2 (g) ---------> H2CO3 (aq) H2O + SO2 (g) ---------> H2SO3 (aq) H2O + 2NO2 (g) ------------> HNO2 (aq) + HNO3 (aq) The location of limestone deposits varies throughout the country, as do the amounts of industrial acids exposed to Calcium ions, while nontoxic, present a number of significant household and industrial problems. For example, Ca2+ + 2CH3(CH2)15COO-Na+ ----------> 2Na+ + (CH3(CH2)15COO-)2Ca sodium stearate calcium stearate Hard water also accounts for the buildup of "boiler scale" on the insides of teapots, water heaters, and industrial Ca(HCO3)2 (aq) + heat ----------> CaCO3 (s) + CO2 (g) + H2O The calcium carbonate scale must be removed periodically because it reduces heating efficiency by acting as an The analysis for water hardness is based on the chemical reaction of Ca2+ ( and Mg2+) with an ion called The analytical procedure is a titration. In this titration, a known amount of water is measured out and EDTA solution is added drop-wise until just enough is present to completely react with all of the calcium and magnesium ions in the sample. In the project you will measure the total amount of calcium and magnesium ions in The indicator is red in the presence of Mg2+. EDTA reacts with both Ca 2+ and Mg 2+. The indicator turns blue Equations: You will report the results as either parts per million (ppm) of calcium carbonate, CaCO3, even though some of the Experimental Procedures for measuring the General Testing for Water Hardness 1. Add 2.5 mL of water to a 10 mL graduated cylinder 2. Add 6 drops of hardness #1 [ a buffer ] 3. Add 3 drops of hardness #2 4. Add drop by drop hardness #3 until the color Types of tests that must be conducted 1. Test the color change of the indicator. Use 2.5 mL of distilled water to conduct this test. 2. Three trials of the calcium reference solution. 3. Three trials of each local water sample. Calculations 1. Calculate the average number of drops of EDTA used for each set of titrations. 2. Calculate the mg of hardness per drop of EDTA used for the reference solution. .5 mg hardness in ref. sol'n X 2.5 mL of ref. sol'n = mg of hardness 3. Calculate the mg of hardness for each local water supply sample. drops of EDTA X mg of hardness = mg of hardness 4. Finally, convert this into milligrams of hardness per liter of water. This is the normal way of reporting Hardness Chart
** Every drop of hardness #3 = 1 grain of total hardness per gallon of water
Materials Used Hardness #1-Buffer Hardness #2-Dye Hardness #3-Titrate Solution Calcium carbonate reference solution 500 mg / L or .5 mg / mL Other Ideas for Water Hardness Research Projects How effective are various water softeners at removing the total water hardness in our community? |